All sounds like general wear and tear items to me.
1. Timing belt and waterpump, do them as a kit, don't ask anyone what you should be looking for etc, just do it. 95,000km, they are due at 105,000km/7 years whichever comes first regardless of condition, yours are almost due so get them done and dusted, alot better alternative and CHEAPER than to leave it because it looked 'OK' then having it snap.
2. CV boots are general wear and tear.
3. Brake discs are also general wear and tear, you can go new pads - old discs, but you cannot/not adviseable to go new discs - old pads, so replace both PADS and DISCS if you need to replace your discs.
4. What reasoning/diagnostic process has your mechanic gone through to state that the 02 sensor requires replacing?
5. No a thermostat is not a coolant temperature sensor, google 'thermostat' to get a picture of what it is, best to have your mechanic replace it.
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